PREFACE TO THE SIXTH EDITION ................................... ix
ABBREVIATIONS .................................................. xi
1. Applications in Coordination Chemistry ....................... 1
1.1. Ammine, Amido, and Related Complexes .................... 1
1.2. Complexes of Ethylenediamine and Related Ligands ....... 14
1.3. Complexes of Pyridine and Related Ligands .............. 23
1.4. Complexes of Bipyridine and Related Ligands ............ 29
1.5. Metalloporphyrins ...................................... 37
1.6. Metallochlorins, Chlorophylls, and
Metallophthalocyanines ................................. 45
1.7. Nitro and Nitrito Complexes ............................ 52
1.8. Lattice Water and Aquo and Hydroxo Complexes ........... 57
1.9. Complexes of Alkoxides, Alcohols, Ethers, Ketones,
Aldehydes, Esters, and Carboxylic Acids ................ 62
1.10.Complexes of Amino Acids, EDTA, and Related Ligands .... 67
1.11.Infrared Spectra of Aqueous Solutions .................. 74
1.12.Complexes of Oxalato and Related Ligands ............... 79
1.13.Complexes of Sulfate, Carbonate, and Related Ligands ... 84
1.14.Complexes of p-Diketones ............................... 96
1.15.Complexes of Urea, Sulfoxides, and Related Ligands .... 105
1.16.Cyano and Nitrile Complexes ........................... 110
1.17.Thiocyanato and Other Pseudohalogeno Complexes ........ 120
1.18.Complexes of Carbon Monoxide .......................... 132
1.19.Complexes of Carbon Dioxide ........................... 152
1.20.Nitrosyl Complexes .................................... 155
1.21.Complexes of Dioxygen ................................. 161
1.22.Metal Complexes Containing Oxo Groups ................. 175
1.23.Complexes of Dinitrogen and Related Ligands ........... 183
1.24.Complexes of Dihydrogen and Related Ligands ........... 189
1.25.Halogeno Complexes .................................... 193
1.26.Complexes Containing Metal-Metal Bonds ................ 199
1.27.Complexes of Phosphorus and Arsenic Ligands ........... 206
1.28.Complexes of Sulfur and Selenium Ligands .............. 210
References ................................................. 222
2. Applications in Organometallic Chemistry ................... 275
2.1. Methylene, Methyl, and Ethyl Compounds ................ 275
2.2. Vinyl, Allyl, Acetylenic, and Phenyl Compounds ........ 281
2.3. Halogeno, Pseudohalogeno, and Acido Compounds ......... 283
2.4. Compounds Containing Other Functional Groups .......... 290
2.5. π-Bonded Complexes of Olefins, Acetylenes, and
Related Ligands ....................................... 294
2.6. Cyclopentadienyl Compounds ............................ 302
2.7. Cyclopentadienyl Compounds Containing Other Groups .... 308
2.8. Complexes of Other Cyclic Unsaturated Ligands ......... 313
2.9. Miscellaneous Compounds ............................... 318
References ................................................. 319
3. Applications in Bioinorganic Chemistry ..................... 333
3.1. Myoglobin and Hemoglobin .............................. 335
3.2. Ligand Binding to Myoglobin and Hemoglobin ............ 340
3.3. Cytochromes and Other Heme Proteins ................... 350
3.4. Bacteriochlorophylls .................................. 359
3.5. Hemerythrins .......................................... 363
3.6. Hemocyanins ........................................... 368
3.7. Blue Copper Proteins .................................. 373
3.8. Iron-Sulfur Proteins .................................. 378
3.9. Interactions of Metal Complexes with Nucleic Acids .... 387
References ................................................. 393
Index ......................................................... 403
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