1. Short Review of NMR Theory ................................... 1
1.1. Origin of the Spectrum .................................. 1
1.2. Coupling to other Nuclei ................................ 5
Bibliography ................................................. 6
2. The Range of Chemical Shifts, Coupling Constants,
and What Influences Each ..................................... 7
2.1. Chemical Shift Values ................................... 9
2.2. Coupling Constants ..................................... 15
2.2.1. Coupling to Hydrogen ............................ 16
2.2.2. Coupling to Carbon .............................. 18
2.2.3. Coupling to Phosphorus .......................... 21
2.2.4. Coupling to Metals .............................. 22
Bibliography ................................................ 23
3. Oxidation State from P(-III) over P(0) to P(+V) ............. 25
Bibliography ................................................ 29
4. λ5-Phosphanes ............................................... 31
Bibliography ................................................ 35
5. λ3-Phosphanes ............................................... 37
5.1. Phosphorus Element Single Bonds ........................ 37
Box Story: Electronic and Steric Properties of
Phosphanes and Phosphites .............................. 44
5.2. Phosphorus Carbon Multiple Bonds ....................... 47
5.3. Phosphorus Phosphorus Bonds ............................ 59
5.3.1. Diphosphanes .................................... 60
5.3.2. Diphosphenes .................................... 65
Bibliography ................................................ 68
6. Main Group Compounds ........................................ 71
6.1. As Lewis Base .......................................... 71
6.2. As Lewis Acid P(I), P(III), and P(V) ................... 75
Bibliography ................................................ 81
7. Transition Metal Complexes .................................. 83
7.1. Phosphanes ............................................. 83
7.2. Chelate Phosphanes (Influence of Ring Size) ............ 87
7.3. Phosphides (Terminal and Bridging) ..................... 89
7.4. Phosphinidines (Terminal and Bridging) ................ 101
7.5. Phosphaacetylene Complexes ............................ 112
7.6. Agostic M-P-H Interactions ............................ 115
7.7. Naked Phosphorus ...................................... 117
Box Story: Isolobal Theory ................................. 125
Bibliography ............................................... 126
Index ......................................................... 129
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