 | Tschulik K. Electrochemical deposition of metallic layers and structures in magnetic gradient fields: Diss. … Dr. rer. nat. - Dresden: Techn. Univ. Dresden, 2012. - iii, 48 p., p.iv-ix: ill., graph. - Ref.: p.39-47.
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1 INTRODUCTION ................................................. 1
2 STATE OF KNOWLEDGE ........................................... 3
2.1 Fundamentals of Electrodeposition ....................... 3
2.2 Important Forces in Magnetoelectrochemistry ............. 6
2.3 Influence of Homogenous Magnetic Fields on
Electrochemical Processes ............................... 9
2.3.1 Magnetic Field Effects on Charge Transfer
Kinetics ......................................... 9
2.3.2 Magnetic Field Effects on Mass Transport ........ 10
2.3.3 Magnetic Field Effects on Corrosion ............. 13
2.3.4 Influences of Homogeneous Magnetic Fields on
the Metal Deposition ............................ 14
2.4 Influence of Inhomogeneous Magnetic Fields on
Electrochemical Processes .............................. 17
2.4.1 Mass transport in inhomogeneous magnetic
fields .......................................... 17
2.4.2 The impact of magnetic field gradients on
corrosion ....................................... 18
2.4.3 Effects of Inhomogeneous Magnetic Fields on
Electrodeposition ............................... 19
3 SUMMARY OF THE MAIN RESULTS ................................. 22
3.1 Experimental Approaches ................................ 22
3.1.1 Electrochemical Setup ........................... 22
3.1.2 Generation of Magnetic Field Gradients .......... 23
3.1.3 Electrolytes .................................... 25
3.1.4 Electrochemical Methods ......................... 26
3.1.5 Characterization Methods ........................ 28
3.2 "Magnetoelectrochemical Surface Structuring:
Electrodeposition of Structured Metallic Layers in
Magnetic Gradient Fields" .............................. 29
3.3 "Effects of well-defined magnetic field gradients on
the electrodeposition of copper and bismuth" ........... 30
3.4 "Studies on the patterning effect of copper deposits
in magnetic gradient fields" ........................... 31
3.5 "In Situ Analysis of Three-Dimensional Electrolyte
Convection Evolving during the Electrodeposition of
Copper in Magnetic Gradient Fields" .................... 32
3.6 "How to obtain structured metal deposits from
diamagnetic ions in magnetic gradient fields?" ......... 33
3.7 "Clarifying the Mechanism of Reverse-Structuring
During Electrodeposition in Magnetic Gradient Fields" .. 34
3.8 "Electrodeposition of separated 3D metallic
structures by pulse-reverse plating in magnetic
gradient fields" ....................................... 35
4 RESUME ...................................................... 38
5 REFERENCES .................................................. 39
6 RELEVANT PUBLICATIONS ....................................... 48
7 APPENDIX .................................................... IV
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