Preface ........................................................ ix
Preface to the Second Edition .................................. xi
Preface to the First Edition ................................. xiii
Contributors ................................................... xv
1 Catalytic Asymmetric Synthesis in Nonconventional Media/
Conditions ................................................... 1
Chikako Ogawa and Shu Kobayashi
2 Asymmetric Organocatalysis .................................. 37
2A Enantioselective Organocatalysis Involving Iminium,
Enamine, SOMO, and Photoredox Activation ................ 39
Allan J.B. Watson and David W. C. MacMillan
2B Asymmetric Acid-Base Bifunctional Catalysis with
Organic Molecules ....................................... 59
Yi Wang and Li Deng
2C Asymmetric Phase-Transfer and Ion Pair Catalysis ........ 95
Seiji Shirakawa and Keiji Maruoka
3 Chiral Lewis Acids and Brønsted Acids in Asymmetric
Synthesis .................................................. 119
Hisashi Yamamoto and Cheol Hong Cheon
4 Asymmetric Synthesis through C-H Activation ................ 163
Huw M. L. Davies and Jørn Hansen
5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions ........ 227
Yoshiji Takemoto and Hideto Miyabe
6 Enzyme-Catalyzed Asymmetric Synthesis ...................... 269
Harald Gröger
7 Transition Metal-Catalyzed Homogeneous Asymmetric
Hydrogenation .............................................. 343
Gao Shang, Wei Li, and Xumu Zhang
8 Asymmetric Carbon-Carbon Bond-Forming Reactions ............ 437
8A Catalytic Asymmetric Conjugate Addition ................ 439
Jian-Xin Ji and Albert S.C. Chan
8B Enantioselective Allylic Substitutions with Carbon
Nucleophiles ........................................... 497
Günter Helmchen, Uli Kazmaier, and Sebastian Förster
8C Asymmetric Carbometallation and Carbocyclizations ...... 643
Iwao Ojima, Joseph J. Kaloko, Stephen J. Chaterpaul,
Yu-Han Gary Teng, and Chi-Feng Lin
8D Asymmetric Ene Reactions and Cycloadditions ............ 683
Koichi Mikami and Kohsuke Aikawa
8E Catalytic Enantioselective Olefin Metathesis
Reactions .............................................. 739
Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek,
and Adil R. Zhugralin
9 Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds
and Related Reactions ...................................... 771
Jin Wook Han and Tamio Hayashi
10 Asymmetric Carbonylations .................................. 799
Cyril Godard, Aurora Ruiz, Montserrat Diéguez, Oscar
Pàmies, and Carmen Claver
11 Asymmetric Oxidations and Related Reactions ................ 839
Kazuhiro Matsumoto and Tsutomu Katsuki
12 Asymmetric Amplification and Autocatalysis ................. 891
Kenso Soai, Tsuneomi Kawasaki, and Takanori Shibata
13 Asymmetric Polymerization .................................. 931
Shingo Ito and Kyoko Nozaki
Index ......................................................... 987
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