Biochemistry of plant secondary metabolism / ed. by M.Wink. - 2nd ed. - Oxford: Wiley-Blackwell, 2010. - xv, 445 p., [18] p. of plates: ill. (some col.). - (Annual plant reviews; Vol.40). - Incl. bibl. ref. - Ind.: p.434-445. - ISBN 978-1-4051-8397-0  Место хранения:   063 | Библиотека по химическим аспектам охраны окружающей среды при Институте органической химии им. Н.Н.Ворожцова. | Новосибирск

Оглавление / Contents

Contributors .................................................... x Preface ...................................................... xiii 1. Introduction: biochemistry, physiology and ecological functions of secondary metabolites ........................... 1 Michael Wink 1.1. Introduction ............................................ 1 1.2. Biosynthesis ............................................ 2 1.3. Transport, storage and turnover ......................... 9 1.4. Costs of secondary metabolism .......................... 13 1.5. Ecological role of secondary metabolites ............... 14 References .................................................. 17 2. Biosynthesis of alkaloids and betalains ..................... 20 Margaret F. Roberts, Dieter Strack and Michael Wink 2.1. Introduction ........................................... 20 2.2. Nicotine and tropane alkaloids ......................... 23 2.3. Pyrrolizidine alkaloids (PAs) .......................... 33 2.4. Benzylisoquinoline alkaloids ........................... 35 2.5. Monoterpene indole alkaloids (MIA) ..................... 46 2.6. Ergot alkaloids ........................................ 56 2.7. Acridone alkaloid biosynthesis ......................... 60 2.8. Purine alkaloids ....................................... 61 2.9. Taxol .................................................. 62 2.10.Betalains .............................................. 66 2.11.Conclusions ............................................ 75 References .................................................. 75 3. Biosynthesis of cyanogenic glycosides, glucosinolates and non-protein amino acids ..................................... 92 Dirk Selmar 3.1. Introduction ........................................... 93 3.2. Cyanogenic glycosides .................................. 94 3.3. Glucosinolates ........................................ 128 3.4. Non-protein amino acids ............................... 146 Acknowledgements ........................................... 157 References ................................................. 157 4. Biosynthesis of phenylpropanoids and related compounds .................................................. 182 Maike Petersen, Joachim Hans and Ulrich Matern 4.1. Introduction .......................................... 182 4.2. General phenylpropanoid pathway and formation of hydroxycinnamate conjugates ........................... 183 4.3. Coumarins ............................................. 197 4.4. Lignans ............................................... 209 4.5. Gallotannins and ellagitannins ........................ 223 4.6. Conclusion ............................................ 229 References ................................................. 230 5. Biochemistry of terpenoids: monoterpenes, sesquiterpenes and diterpenes ............................................. 258 Mohamed Ashour, Michael Wink and Jonathan Gershenzon 5.1. Introduction .......................................... 259 5.2. Function .............................................. 260 5.3. Biosynthesis .......................................... 263 5.4. Conclusions ........................................... 285 References ................................................. 286 6. Biochemistry of sterols, cardiac glycosides, brassinosteroids, phytoecdysteroids and steroid saponins ................................................... 304 Wolfgang Kreis and Frieder Müller-Uri 6.1. Introduction .......................................... 305 6.2. Sterols ............................................... 308 6.3. Cardiac glycosides .................................... 319 6.4. Brassinosteroids ...................................... 336 6.5. Phytoecdysteroids ..................................... 341 6.6. Steroid saponins and steroid alkaloids ................ 343 6.7. Conclusions ........................................... 347 References ................................................. 348 7. Chemotaxonomy seen from a phylogenetic perspective and evolution of secondary metabolism .......................... 364 Michael Wink, Flavia Botschen, Christina Gosmann, Holger Schäfer and Peter G. Waterman 7.1. Introduction .......................................... 365 7.2. Establishment of chemotaxonomy as a research discipline ............................................ 365 7.3. Developments in small molecule chemotaxonomy over the past 35 years ..................................... 380 7.4. Molecular biology and plant taxonomy .................. 382 7.5. Comparison between patterns of secondary metabolites and molecular phylogeny ............................... 383 7.6. Evolution of plant secondary metabolism ............... 406 Acknowledgements ........................................... 426 References ................................................. 426 Index ......................................................... 434 Color plate can be found between pages 368 and 369.