Preface ...................................................... xiii
Overview
1 Controlled/Living Radical Polymerization: State of the Art
in 2005 ...................................................... 2
Krzysztof Matyjaszewski
Atom Transfer Radical Polymerization: Mechanisms and Materials
2 Living Radical Polymerization Catalyzed with Hydrophilic
and Thermosensitive Ruthenium(II) Complexes in Aqueous
Media ....................................................... 14
Toshihide Yoshitani, Yasuhiro Watanabe, Tsuyoshi Ando,
Masami Kamigaito, and Mitsuo Sawamoto
3 Stereospecific Living Radical Polymerization ................ 26
Masami Kamigaito, Kotaro Satoh, Decheng Wan, Yuya
Sugiyama, Kazuhiko Koumura, Takuya Shibata, and Yoshio
Okamoto
4 Controlled Radical Polymerization of Vinyl Monomers
Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes ..... 40
Sebastien Delfosse, Aurore Richel, Lionel Delaude,
Albert Demonceau, and Alfred F. Noels
5 Factors Determining the Performance of Copper-Based Atom
Transfer Radical Polymerization Catalysts and Criteria
for Rational Catalyst Selection ............................. 56
Nicolay V. Tsarevsky, Wei Tang, Samuel J. Brooks,
and Krzysztof Matyjaszewski
6 Magnetic Nanoparticle Supported Catalyst for Atom
Transfer Radical Polymerization of Methyl Methacrylate ...... 71
Shijie Ding, Maciej Radosz, and Youqing Shen
7 Loss in Activity and Catalyst Recyclability in Batch and
Continuous Supported Atom Transfer Radical Polymerization ... 85
Santiago Faucher and Sniping Zhu
8 Alkylated Linear Amine Ligands for Homogeneous Atom
Transfer Radical Polymerization ............................. 97
Metin H. Acar, C. Remzi Becer, H. Alper Ondur,
and Sebnem Inceoğlu (Carol, a dot over the I if you
can)
9 Electron Spin Resonance Study of Methacrylate Radicals
Generated from Purified Oligomers Prepared by Atom
Transfer Radical Polymerization ............................ 111
Atsushi Kajiwara
10 Ti-Catalyzed Living Radical Polymerization of Styrene
Initiated by Epoxide Radical Ring Opening .................. 125
Alexandru D. Asandei, Isaac W. Mpran, Gobinda Saha,
and Yanhui Chen
11 Click Functionalization of Well-Defined Copolymers
Prepared by Atom Transfer Radical Polymerization ........... 140
Brent S. Sumerlin, Nicolay V. Tsarevsky, Haifeng Gao,
Patricia Golas, Guillaume Louche, Robert Y. Lee,
and Krzysztof Matyjaszewski
12 Polymers with Pendant Allyl Ester Groups Prepared
via Atom Transfer Radical Polymerization: Synthesis,
Characterization, and Microstructuring of Thin Films ....... 153
René Nagelsdiek, Petra Mela, Martina Mennicken, Helmut
Keul, and Martin Möller
13 Controlled Radical Polymerization of 1-Ethoxyethyl
(Meth)acrylate: Novel Route for the Synthesis of
Poly((meth)acrylic acid) Containing Polymer Structures ..... 171
Wim Van Camp and Filip E. Du Prez
14 Novel Organo-Soluble or Water-Soluble Copolymers
Containing DNA Nucleobases ................................. 185
Jean-François Lutz, Rainer Nehring, and Sebastian
Pfeifer
15 Conjugates of Polymers and Sequence-Defined Polypeptides
via Controlled Radical Polymerization ...................... 198
Mattijs G. J. Ten Cate and Hans G. Börner
16 Synthesis and Characterization of Methacrylate-Type
Glycopolymers with Branched Architectures .................. 214
Sharmila Muthukrishnan, Hideharu Mori, and Axel
H.E. Müller
17 Acrylate-Based Block Copolymers Prepared by Atom Transfer
Radical Polymerization as Matrices for Drug Delivery
Applications ............................................... 234
Robert E. Richard, Marlene Schwarz, Shrirang Ranade,
A. Ken Chan, Krzysztof Matyjaszewski, and Brent
Sumerlin
18 Grafting Chromatographic Stationary Phase Substrates
by Atom Transfer Radical Polymerization .................... 252
Patrick McCarthy, Nicolay V. Tsarevsky, Lindsay
Bombalski, Krzysztof Matyjaszewski, and Christopher
Pohl
19 Synthesis of Inorganic-Polymer Nanocomposites by Atom
Transfer Radical Polymerization Using Initiators or
Polymerizable Groups Attached to Transition Metals via
Bidentate Ligands .......................................... 269
Guido Kickelbick, Dieter Holzinger, Dieter Rutzinger,
and Sorin Ivanovici
20 Surface Modification of Inorganic Nanotubes by Atom
Transfer Radical Polymerization ............................ 279
Yuan Gao and Deyue Yan
21 Advances in Nanostructured Carbons from Block Copolymers
Prepared by Controlled Radical Polymerization Techniques ... 295
Tomasz Kowalewski, Chuanbing Tang, Michal Kruk, Bruno
Dufour, and Krzysztof Matyjaszewski
Nitroxide Mediated Polymerization and Other Stable Free
Radical Polymerization
22 An Overview of the Emulsion Stable Free Radical
Nanoprecipitation Polymerization Process ................... 312
Andrea R. Szkurhan and Michael K. Georges
23 Crowded Phosphonylated Alkoxyamines with Low Dissociation
Temperatures: A Milestone in Nitroxide-Mediated
Polymerization ............................................. 326
Florence Chauvin, Jean-Luc Couturier, Pierre-Emmanuel
Dufils, Pierre Gérard, Didirr Gigmes, Olivier Guerret,
Yohann Guillaneuf, Sylvain R. A. Marque, Denis Bertin,
and Paul Tordo
24 Reactive Block Copolymers as Versatile Compatibilizers ..... 342
Leticia Flores-Santos, Alfonso González-Montiel, and
Enrique Saldivar-Guerra
25 Living Radical Polymerizations Mediated by Metallo
Radical and Organo-Transition Metal Complexes .............. 358
Bradford B. Wayland, Xuefeng Fu, Chi-How Peng, Zhi Lu,
and Michael Fryd
26 Cobalt-Mediated Radical Polymerization of Vinyl Acetate:
A New Tool for Macromolecular Engineering .................. 372
Antoine Debuigne, Christophe Detrembleur, Rayna
Bryaskova, Jean-Raphaёl Caille, and Robert Jérôme
27 Borane-Mediated Control Radical Polymerization: Synthesis
of Chain End Functionalized Fluoropolymers ................. 387
Т.С. Chung, H. Hong, Z.С. Zhang, and Z.M. Wang
Reversible Addition Fragmentation Chain Transfer and Other
Degenerative Transfer Processes
28 An Ab Initio Guide to Structure-Reactivity Trends
in Reversible Addition Fragmentation Chain Transfer
Polymerization ............................................. 406
Elizabeth H. Krenske, Ekaterina I. Izgorodina, and
Michelle L. Coote
29 Tailoring Molecular Weight Distribution and Structure
with Difunctional Reversible Addition Fragmentation Chain
Transfer Agent. A Model Study .............................. 421
Geoffrey Johnston-Hall and Michael J. Monteiro
30 Progress in RAFT/MADIX Polymerization. Synthesis, Use,
and Recovery of Chain Transfer Agents ...................... 438
Sebastien Perrier, Pittaya Takolpuckdee, Steven Brown,
Thomas M. Legge, Debashish Roy, Murray R. Wood,
Steven P. Rannard, and David J. Duncalf
31 Pulsed-Laser Initiated Reversible Addition Fragmentation
Chain Transfer Polymerization .............................. 455
M. Buback, T. Junkers, and P. Vana
32 Tailor-Made Copolymers via Reversible Addition
Fragmentation Chain Transfer the Fast Way .................. 473
Richard Hoogenboom, Martin W. M. Fijten, Renzo M.
Paulus, and Ulrich S. Schubert
33 Obtaining Chain Length Dependent Termination Rate
Coefficients via Thermally Initiated Reversible Addition
Fragmentation Chain Transfer Experiments: Current Status
and Future Challenges ...................................... 486
Alexander Theis, Martina H. Stenzel, Thomas P. Davis,
and Christopher Barner-Kowollik
34 Reversible Addition Fragmentation Chain Transfer-Mediated
Copolymerizations: The Challenge of Random Copolymer
Blocks ..................................................... 501
Bert Klumperman, James B. McLeary, Eric T.A.
van den Dungen, Willem-Jan Soer, and Jelena S. Božović
35 RAFT Copolymerization and Its Application to the Synthesis
of Novel Dispersants-Intercalants-Exfoliants for Polymer-
Clay Nanocomposites: Some Interesting Results from RAFT
(Co)polymerization ......................................... 514
Graeme Moad, Guoxin Li, Rudolf Pfaendner, Almar
Postma, Ezio Rizzardo, San Thang, and Hendrik Wermter
36 Controlled Synthesis of Amino Acid-Based Polymers
by Reversible Addition Fragmentation Chain Transfer
Polymerization ............................................. 533
Hideharu Mori, Kazuhiko Sutoh, Hideyuki Iwaya, Atsushi
Nagai, and Takeshi Endo
37 Applications of Telechelic Reversible Addition
Fragmentation Chain Transfer Polymers ...................... 547
John Lai, Dave Egan, Raymond Hsu, Carole Lepilleur,
Alex Lubnin, Anthony Pajerski, and Ronald Shea
38 Various Strategies for the Chemical Transformation of
Xanthate-Functional Chain Termini in MADIX Copolymers ...... 564
Mathias Destarac, Chakib Kalai, Agnieszka Wilczewska,
Laurence Petit, Eric Van Gramberen, and Samir Z. Zard
39 Direct Synthetic Strategies to Hydrophilic Starlike
Polymers by MADIX .......................................... 578
Daniel Taton, Jean-François Baussard, Ludovic
Dupayage, Yves Gnanou, Mathias Destarac, Catherine
Mignaud, and Claire Pitois
40 Germanium- and Tin-Catalyzed Living Radical
Polymerizations of Styrene ................................. 595
Atsushi Goto, Hirokazu Zushi, Yungwan Kwak, and
Takeshi Fukuda
41 Living Radical Ab Initio Emulsion Polymerization of
n-Butyl Acrylate by Reverse Iodine Transfer
Polymerization ............................................. 604
J. Tonnar, P. Lacroix-Desmazes, and B. Boutevin
Indexes
Author Index .................................................. 623
Subject Index ................................................. 627
|
